Black Walnut Hulls (Juglans nigra), the Eastern Black walnut, is a species of flowering tree in the hickory family, Juglandaceae, that is native to eastern North America. It grows mostly in riparian zones, from southern Ontario, west to southeast South Dakota, south to Georgia, northern Florida and southwest to central Texas. Isolated wild trees in the Upper Ottawa Valley may be an isolated native population or may have derived from planted trees.
Black walnut drupes contain juglone (5-hydroxy-1,4-naphthoquinone), plumbagin (yellow quinone pigments), and tannin. The brownish-black dye was used by early settlers to dye hair. Extracts of the outer, soft part of the drupe are still used as a natural dye for handicrafts. The tannins present in walnuts act as a mordant, aiding in the dyeing process, and are usable as a dark ink or wood stain.